Second-order advantage maintenance with voltammetric data modeling for quantitation of ethiofencarb in the presence of interferences.
This work presents the development of a method based on a voltammetric determination coupled to second-order data modeling with multivariate curve resolution-alternating least-square (MCR-ALS) and unfolded partial least squares regression followed by residual bilinearization (U-PLS/RBL) for the quantitation of the pesticide ethiofencarb in the presence of interferences in tap water. The determination of ethiofencarb by voltammetry is possible on the basis that this pesticide is hydrolysed in alkaline media giving rise to a compound which shows an oxidation peak at Ep=0.80 V. But some other pesticides belonging to the same family can be considered as interferences due to the high overlapping in their signals. The two such interferences are fenobucarb and bendiocarb, which have not been included in the calibration step. The possibility of second-order multivariate calibration was studied by using the hydrolysis time as the third variable, and MCR-ALS and U-PLS/RBL. Good results were obtained in this determination in spite of the high overlapping in voltammetric signals.
['Diez|Nielene Mora|NM|', 'Cabanillas|Agustina Guiberteau|AG|', 'Silva Rodríguez|Antonio|A|', 'Goicoechea|Héctor C|HC|']
D000465:Algorithms D002138:Calibration D002219:Carbamates D060766:Drinking Water D055664:Electrochemical Techniques D006801:Humans D006868:Hydrolysis D016018:Least-Squares Analysis D010575:Pesticides D048448:Phenylcarbamates D014874:Water Pollutants, Chemical
Ethiofencarb Unfolded partial least squares regression followed by residual bilinearization Voltammetry Differential pulsed voltammetry Multivariate curve resolution