Highly Selective Electrochemiluminescence Sensor Based on Molecularly Imprinted-quantum Dots for the Sensitive Detection of Cyfluthrin.
A highly selective and sensitive molecularly imprinted electrochemiluminescence (MIECL) sensor was developed based on the multiwall carbon nanotube (MWCNT)-enhanced molecularly imprinted quantum dots (MIP-QDs) for the rapid determination of cyfluthrin (CYF). The MIP-QDs fabricated by surface grafting technique exhibited excellent selective recognition to CYF, resulting in a specific decrease of ECL signal at the MWCNT/MIP-QD modified electrode. Under optimal conditions, the MIECL signal was proportional to the logarithm of the CYF concentration in the range of 0.2 µg/L to 1.0 × 103 µg/L with a determination coefficient of 0.9983. The detection limit of CYF was 0.05 µg/L, and good recoveries ranging from 86.0% to 98.6% were obtained in practical samples. The proposed MIECL sensor provides a novel, rapid, high sensitivity detection strategy for successfully analyzing CYF in fish and seawater samples.
['Xu|Jinjin|J|', 'Zhang|Rongrong|R|', 'Liu|Chenxi|C|', 'Sun|Aili|A|', 'Chen|Jiong|J|', 'Zhang|Zeming|Z|', 'Shi|Xizhi|X|']
electrochemiluminescence sensor cyfluthrin quantum dot fish samples molecularly imprinted polymers