Unprecedented trinuclear Ag(I) complex with 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine as an efficient catalyst for the aziridination of olefins.
An unprecedented trinuclear heteroleptic Ag(I) complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins.
['Safin|Damir A|DA|', 'Pialat|Amélie|A|', 'Korobkov|Ilia|I|', 'Murugesu|Muralee|M|']
aziridination olefins catalysis crystal structure silver cluster