A reversible multi-stimuli-responsive fluorescence probe and the design for combinational logic gate operations.
Here, a novel multi-stimuli-responsive fluorescence probe is developed by incorporating spiropyran group into the coumarin-substituted polydiacetylene (PDA) vesicles. The fluorescence of PDA can be turned on upon heating, and can be quenched upon exposure to UV light irradiation or pH stimuli owing to the fluorescene resonance energy transfer (FRET) between the red-phase PDA and the open merocyanine (MC) form of spiropyran. Moreover, we have designed and experimentally realized a set of logic gate operations for the first time based on the fluorescence modulation of the designed system upon thermal, photo, and pH stimuli. This novel type of resettable logic gates augur well for practical applications in information storage, optical recording, and sensing in complicated microenvironments.
['Xia|Hongyan|H|', 'Xu|Yangyang|Y|', 'Yang|Guang|G|', 'Jiang|Hao|H|', 'Zou|Gang|G|', 'Zhang|Qijin|Q|']
D001578:Benzopyrans D005453:Fluorescence D031541:Fluorescence Resonance Energy Transfer D005456:Fluorescent Dyes D007211:Indoles D015335:Molecular Probes D009574:Nitro Compounds
fluorescence probe logic gate PDA vesicles stimuli- responsive