Removal of Pb(II) from contaminated waters using cellulose sulfate/chitosan aerogel: Equilibrium, kinetics, and thermodynamic studies.
In this study, the cellulose sulfate/chitosan aerogel (CCA) was prepared by chitosan and sulfonated cotton, and its efficiency was assessed for lead removal from contaminated waters. The adsorbent was determined by FESEM, EDS, FTIR, and BET analysis. The batch experiments were designed by Design-Expert software. At an initial lead concentration of 300 mg L-1, the contact time of 40 min, and the temperature of 26 °C, the maximum adsorption capacity and the removal efficiency were 137.8 mg g-1 and 91.9%, respectively. Also, the effect of ions including cations and anions at 100 mg L-1 was investigated, and it was found that the presence of anions does not have much effect on adsorption, but among cations, calcium and magnesium have the inhibitor effect on adsorption due to their double plosive. Adsorption isotherms were studied at different temperatures, and the kinetics of the reaction were investigated at different concentrations. Thermodynamic parameters indicated that the adsorption process was spontaneous, endothermic, and increasing irregularity at the adsorbent level. Adsorption recovery was performed five times adsorption and de-adsorption by hydrochloric acid 1 M washing and only 10% of adsorption capacity was decreased.
['Najaflou|Sajjad|S|', 'Rad|Mahsa Forouzesh|MF|', 'Baghdadi|Majid|M|', 'Nabi Bidhendi|Gholam Reza|GR|']
D000327:Adsorption D002482:Cellulose D048271:Chitosan D006863:Hydrogen-Ion Concentration D007700:Kinetics D007854:Lead D013696:Temperature D013816:Thermodynamics D014874:Water Pollutants, Chemical D018508:Water Purification
Cellulose Chitosan Lead Adsorption Water treatment