Surface modification of zero-valent iron nanoparticles with β-cyclodextrin for 4-nitrophenol conversion.
Environmental pollution causes irreversible damage to ecosystems and their structure. Therefore, the development of novel remedial techniques is a must for an effective response to emerging contaminants and those already persisting in the environment. The nanosized zero-valent iron (nZVI) is considered as an important nanostructure for the degradation of toxic compounds. Furthermore, the degradative potential of nZVI may be improved by surface modification. In this work nZVI was functionalized with β-cyclodextrin (β-CD), which is considered to be an environmentally-friendly and cheap adsorbent for toxic pollutants. Such a 'green' improvement not only enhances the activity of nZVI but also enables the conversion of 4-nitrophenol to 4-aminophenol, which under standard conditions is persistent and does not significantly react with bare nZVI. This research may help to find a solution to treat persistent organic pollutants (POPs) in aqueous environment.
['Krawczyk|Kamil|K|', 'Wacławek|Stanisław|S|', 'Silvestri|Daniele|D|', 'Padil|Vinod V T|VVT|', 'Řezanka|Michal|M|', 'Černík|Miroslav|M|', 'Jaroniec|Mietek|M|']
Zero-valent iron Cyclodextrins Modified particles Water and wastewater treatment