Novel Two-Dimensional WO3/Bi2W2O9 Nanocomposites for Rapid H2S Detection at Low Temperatures.
Compared with single-component metal oxides, multicomponent metal oxides show good gas sensing performance in the field of gas sensing, but they still need to be further improved in terms of rapid response. In this paper, a two-dimensional flaky WO3/Bi2W2O9 composite material with a thickness of about 32.3 nm was synthesized by a simple solvothermal method. The composite has good sensing performance and selectivity toward H2S. When the operating temperature is as low as 92 °C, the response to 100 ppm H2S reaches 84.18, and the response time is 2 s, which is extremely fast due to the open system of the two-dimensional nanosheet. A combination of gas chromatography-mass spectrometry (GC-MS) and X-ray photoelectron spectroscopy (XPS) is used to analyze the changes of H2S and the surface chemistry of WO3/Bi2W2O9 composite materials; the sensing mechanism of H2S was studied by a Kelvin probe and UV diffuse reflection. Compared with the pure phase WO3 and Bi2W2O9, good gas sensing properties of the WO3/Bi2W2O9 composite may be due to its unique heterostructure. This is the first application of WO3/Bi2W2O9 in the field of gas sensing and is of great significance for the rapid detection of H2S at low temperatures for multicomponent metal oxides.
['Zhang|Yu|Y|', 'Zhang|Xianfa|X|', 'Guo|Chuanyu|C|', 'Xu|Yingming|Y|', 'Cheng|Xiaoli|X|', 'Zhang|Fangdou|F|', 'Major|Zoltán|Z|', 'Huo|Lihua|L|http://orcid.org/0000-0003-1725-0148']
two-dimensional WO3/Bi2W2O9 composite sensing mechanism heterostructure H2S sensing properties