Integrating organic micropollutant removal into tertiary filtration: Combining PAC adsorption with advanced XXXX removal.

@entity34200 @entity3522 @entity207 @entity8821 @entity505 @entity3151 @entity2049 @entity23135
UNASSIGNED: Direct addition of powdered activated @entity505 (PAC) to a deep-bed filter was investigated at pilot-scale as a single advanced treatment stage for simultaneous removal of organic micropollutants (OMPs) and @entity3151 from secondary effluent. PAC doses of 10-50  mg/L were assessed with regard to their impacts on filter performance and removal of 15 selected OMPs over a period of 18 months. The PAC was effectively retained by the filter and had no negative effect on filter head loss. Filter runtime until particle breakthrough depended mainly on coagulant dose and did not decrease significantly due to the additional PAC load. Removal of suspended solids and @entity3151 by coagulation was effective independent of the PAC dose. A PAC dose of 35  mg/L PAC was suitable to remove well-adsorbing OMPs (e.g. @entity2049 , @entity3522 ) by >80% and medium adsorbing OMPs (e.g. @entity8821 , @entity207 ) by 50-80%. Median removals were 50-80% for well-adsorbing and 30-50% for medium adsorbing OMPs with 20  mg/L PAC. Abatement of all OMPs was low (<50%) with 10  mg/L PAC, possibly because of the high effluent organic matter content (median dissolved organic @entity505 (DOC) concentrations of 11.2  mg/L). In addition to adsorptive removal, relevant concentration decreases of certain OMPs (e.g. @entity23135 ) were attributed to biological transformation in the filter. Adsorption onto accumulating PAC in the top layer of the filter bed led to improved @entity34200 adsorption with increasing filter runtime. The comparison of @entity34200 removal in the pilot filter with laboratory adsorption tests demonstrates that batch test results can be applied to estimate adsorptive @entity34200 removal in real applications.
